Characterization of iodonium salts differing in the anion

被引：24

作者：

Gu, HY

Ren, KT

Grinevich, O

Malpert, JH

Neckers, DC ^{[1
]}

机构：

[1] Bowling Green State Univ, Ctr Photochem Sci, Bowling Green, OH 43403 USA

[2] Spectral Grp Ltd Inc, Maumee, OH 43537 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 66卷 / 12期

关键词：

D O I：

10.1021/jo0015725

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

The properties and reactivity of a series of iodonium salts with different anions were compared. The nucleophilicity of the anions in such compounds can be characterized by their melting points and NMR spectra. When using Quinaldine Red as indicator and CH3CN as solvent, the acid release rate of the iodonium salts correlated very well with their polymerization results in acid-sensitive epoxides.

引用

页码：4161 / 4164

页数：4

共 14 条

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2-U

[3]

DIARYLIODONIUM SALTS - NEW CLASS OF PHOTO-INITIATORS FOR CATIONIC POLYMERIZATION [J].