Syngas production from methane in an electrochemical membrane reactor

被引：27

作者：

Sobyanin, VA ^{[1
]}

Belyaev, VD ^{[1
]}

Gal'vita, VV ^{[1
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

来源：

CATALYSIS TODAY | 1998年 / 42卷 / 03期

关键词：

methane; partial oxidation; syngas; solid oxide electrolyte cell;

D O I：

10.1016/S0920-5861(98)00111-4

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Electrocatalytic conversion of methane over Ag-, Pt-, Ni- and Pt+CeO2-based electrode-catalysts in a cell with a solid oxygen conducting electrolyte: CH4, electrode-catalyst/0.9ZrO(2) + 0.1Y(2)O(3)\Pt + PrO2,air was studied at 660-850 degrees C and the ratio of methane and electrochemically pumped oxygen flows of 0.8-2.0. Unlike Ag and Pt+CeO2 electrodes, the Ni and Pt electrodes were found to be active electrode-catalysts for partial oxidation of methane to syngas with the concentration ratio of [H-2]/[CO]approximate to 2. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：337 / 340

页数：4

共 6 条

[1] SYNTHESIS GAS-PRODUCTION FROM METHANE OVER AN IRON ELECTRODE IN A SOLID-ELECTROLYTE CELL [J].