Solid state coordination chemistry: two-dimensional oxides constructed from polyoxomolybdate clusters and copper-organoamine subunits

被引:154
作者
Hagrman, D
Sangregorio, C
O'Connor, CJ
Zubieta, J [1 ]
机构
[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA
[2] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 22期
关键词
D O I
10.1039/a806234j
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Copper-organodiamine substructures are effective bridging groups for polyoxomolybdate anions in the construction of two-dimensional mixed metal networks, of which [{Cu(bpe)}(4)(alpha-Mo8O26)]. 2H(2)O and [{Cu(pyrd)}(4)(gamma-H4Mo8O26)] are representative [bpe = 1,2-bis(4-pyridyl)ethylene; pyrd = pyridazine].
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页码:3707 / 3709
页数:3
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