Polymer-supported distannanes:: a new and efficient synthesis of highly effective reagents for iodine atom transfer cyclisations

被引：14

作者：

Hernán, AG ^{[1
]}

Kilburn, JD ^{[1
]}

机构：

[1] Univ Southampton, Sch Chem, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 04期

关键词：

distannane; polymer supported; atom transfer;

D O I：

10.1016/j.tetlet.2003.11.039

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polymeric distannanes were synthesised by the cross-linking of polystyrene bound tin hydride functionalities using a palladium mediated dehydrogenative coupling. The polymers were characterised by spectroscopic methods (IR and C-13, Sn-119 NMR) and elemental analysis and were successfully applied to two iodine atom transfer cyclisations, performing as well as solution based hexaalkylditin reagents and significantly better than previously reported polymer-supported ditin reagents. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：831 / 834

页数：4

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