Bioconcentration of nonylphenol in fathead minnows (Pimephales promelas)

被引:38
作者
Snyder, SA [1 ]
Keith, TL [1 ]
Pierens, SL [1 ]
Snyder, EM [1 ]
Giesy, JP [1 ]
机构
[1] Michigan State Univ, Inst Environm Toxicol, Dept Zool, Natl Food Safety & Toxicol Ctr 218C, E Lansing, MI 48824 USA
关键词
bioaccumulation; alkylphenol; surfactant; bioconcentration factor;
D O I
10.1016/S0045-6535(00)00524-5
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Bioconcentration of p-nonylphenol (NP) by fathead minnows was determined under laboratory conditions. Fish were exposed continuously for 42 days to 0.33, 0.93 and 2.36 mug NP/l in a flow-through system. NP was Soxhlet extracted from whole fish homogenates with dichloromethane (DCM). The resulting extract was concentrated and bulk lipids removed by gel permeation and silica-gel chromatography. Compounds were identified and quantified by reverse-phase high-pressure liquid chromatography (RP-HPLC) with fluorescence detection. Mass spectrometry was used for verification of peak assignments. Bioconcentration factors (BCFs) ranged from 245 to 380. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1697 / 1702
页数:6
相关论文
共 28 条
[1]   PARTITIONING OF ALKYLPHENOLS AND ALKYLPHENOL POLYETHOXYLATES BETWEEN WATER AND ORGANIC-SOLVENTS [J].
AHEL, M ;
GIGER, W .
CHEMOSPHERE, 1993, 26 (08) :1471-1478
[2]   AQUEOUS SOLUBILITY OF ALKYLPHENOLS AND ALKYLPHENOL POLYETHOXYLATES [J].
AHEL, M ;
GIGER, W .
CHEMOSPHERE, 1993, 26 (08) :1461-1470
[3]   BEHAVIOR OF ALKYLPHENOL POLYETHOXYLATE SURFACTANTS IN THE AQUATIC ENVIRONMENT .1. OCCURRENCE AND TRANSFORMATION IN SEWAGE-TREATMENT [J].
AHEL, M ;
GIGER, W ;
KOCH, M .
WATER RESEARCH, 1994, 28 (05) :1131-1142
[4]   Occurrence of alkylphenols and alkylphenol mono- and diethoxylates in natural waters of the Laurentian Great Lakes basin and the upper St Lawrence River [J].
Bennie, DT ;
Sullivan, CA ;
Lee, HB ;
Peart, TE ;
Maguire, RJ .
SCIENCE OF THE TOTAL ENVIRONMENT, 1997, 193 (03) :263-275
[5]  
CAHN A, 1978, KIRK OTHMER ENCY CHE, V22, P365
[6]   Identification of estrogenic chemicals in STW effluent. 1. Chemical fractionation and in vitro biological screening [J].
Desbrow, C ;
Routledge, EJ ;
Brighty, GC ;
Sumpter, JP ;
Waldock, M .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1998, 32 (11) :1549-1558
[7]  
DWYER FJ, 1995, USE SURROGATE SPECIE, P71
[8]   Nonylphenol polyethoxy carboxylate metabolites of nonionic surfactants in US paper mill effluents, municipal sewage treatment plant effluents, and river waters [J].
Field, JA ;
Reed, RL .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1996, 30 (12) :3544-3550
[9]  
GIESY JP, 1998, WAT REPORTS, V97, P90
[10]  
Jobling S, 1996, ENVIRON TOXICOL CHEM, V15, P194, DOI [10.1002/etc.5620150218, 10.1897/1551-5028(1996)015&lt