Efficient sensitization of nanocrystalline TiO2 films with highmolar extinction coefficient ruthenium complex

被引：28

作者：

Jiang, Ke-Jian ^{[1
,2
]}

Xia, Jiang-bin ^{[1
]}

Masaki, Naruhiko ^{[1
]}

Noda, Shuji ^{[2
]}

Yanagida, Shozo ^{[1
]}

机构：

[1] Osaka Univ, Ctr Adv Sci & Innovat, Osaka 5650871, Japan

[2] Shimane Inst Ind Technol, Matsue, Shimane 6900816, Japan

来源：

INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 03期

关键词：

dye-sensitization; ruthenium complex; pi-conjugated;

D O I：

10.1016/j.ica.2007.06.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel heteroleptic polypyridine ruthenium complex, cis-Ru(L1)(L2)(NCS)(2), L1 = 4,4'-dicarboxylic acid-2,2'-bipyridine (dcbpy), L2 = 4,4'-bis[p-diethylamino]-alpha-styryl]-2,2'-bipyridine, was synthesized. The dye displays extremely high molar extinction coefficient, which is comparable with organic dye. Preliminary test shows the dye-sensitized TiO2 solar cell gives high conversion efficiency up to 8.65% under 1 Sun, while 8.35% is given for N3 based DSCs under the same condition. The dye will be further employed in solid state DSCs with hole transport material. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：783 / 785

页数：3

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