Rare and diverse binding modes introduced through mechanical bonding

被引:75
作者
Leigh, DA [1 ]
Lusby, PJ
Slawin, AMZ
Walker, DB
机构
[1] Univ Edinburgh, Sch Chem, Kings Bldg,W Mains Rd, Edinburgh EH9 3JJ, Midlothian, Scotland
[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
关键词
catenanes; coordination modes; hydrogen bonds; noncovalent interactions; rotaxanes;
D O I
10.1002/anie.200500004
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Any which way, but not loose: A range of diverse noncovalent binding interactions are observed with a [2]rotaxane (see structure) and a [2]catenane that are not found with similar but not mechanically interlocked fragments. (C (macrocycle) turquoise, other C atoms yellow, O red, N blue, H gray, F green, S orange.). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:4557 / 4564
页数:8
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