Mn-salen catalyzed asymmetric epoxidation of (+/-)-3-alkylindene: Reagent-dependent stereoselectivity

被引：30

作者：

Noguchi, Y ^{[1
]}

Irie, R ^{[1
]}

Fukuda, T ^{[1
]}

Katsuki, T ^{[1
]}

机构：

[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 81281,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 26期

关键词：

D O I：

10.1016/0040-4039(96)00896-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Epoxidation of (+/-)-3-alkylindenes was examined with various (salen)manganese(III) complexes as catalysts and, from the analysis of the obtained data, it was found that the location and nature of C3- and C3'-substituents of the Mn-catalysts strongly influenced the stereochemistry of the epoxidation. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：4533 / 4536

页数：4

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