Binary tellurium(IV) azides:: Te(N3)4 and [Te(N3)5]-

被引：65

作者：

Klapötke, TM ^{[1
]}

Krumm, B ^{[1
]}

Mayer, P ^{[1
]}

Schwab, I ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 47期

关键词：

azides; fluorides; hazardous materials; tellurium;

D O I：

10.1002/anie.200352656

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Very sensitive materials: Tellurium tetraazide, Te(N3) 4, was prepared directly from TeF4 and Me 3SiN3 as an extremely sensitive solid; azidation of a pentafluorotellurate(IV) anion gave the pentaazidotellurate(IV) anion. The crystal structure of the pyridinium salt [pyH][Te(N3)5] consists of [Te(N3)5]- units, considerably distorted from ideal square-pyramidal symmetry, that are linked through Te⋯N interactions (see picture).

引用

页码：5843 / 5846

页数：4

共 43 条

[1] SIR97:: a new tool for crystal structure determination and refinement [J].

Altomare, A ;

Burla, MC ;

Camalli, M ;

Cascarano, GL ;

Giacovazzo, C ;

Guagliardi, A ;

Moliterni, AGG ;

Polidori, G ;

Spagna, R .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119

[2] NEW PYRIDINE COMPLEXES OF TELLURIUM TETRAFLUORIDE [J].

AYNSLEY, EE ;

HETHERINGTON, G .

JOURNAL OF THE CHEMICAL SOCIETY, 1953, (SEP) :2802-2803

[3] DARSTELLUNG IR- UND ELEKTRONENSPEKTREN VON AZIDO-METALLKOMPLEXEN [J].

BECK, W ;

FEHLHAMM.WP ;

POLLMANN, P ;

SCHUIERE.E ;

FELDL, K .

CHEMISCHE BERICHTE-RECUEIL, 1967, 100 (07) :2335-&

[4]

Beck W, 2001, Z ANORG ALLG CHEM, V627, P1669, DOI 10.1002/1521-3749(200107)627:7<1669::AID-ZAAC1669>3.0.CO

[5]

2-0

[6] AB-INITIO ENERGY-ADJUSTED PSEUDOPOTENTIALS FOR ELEMENTS OF GROUPS 13-17 [J].

BERGNER, A ;

DOLG, M ;

KUCHLE, W ;

STOLL, H ;

PREUSS, H .

MOLECULAR PHYSICS, 1993, 80 (06) :1431-1441

[7] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[8]

DAMIENS A, 1923, ANN CHIM PHYS, V19, P74

[9] STRUCTURE OF A 5-CO-ORDINATE COMPLEX OF IRON - PENTA-AZIDOIRON(III) ION, FE(N3)52- [J].

DRUMMOND, J ;

WOOD, JS .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (23) :1373-&

[10]

Dunning T. H., 1976, MODERN THEORETICAL C

← 1 2 3 4 5 →