White Electroluminescence from Star-like Single Polymer Systems: 2,1,3-Benzothiadiazole Derivatives Dopant as Orange Cores and Polyfluorene Host as Six Blue Arms

被引:61
作者
Chen, Lei [1 ,2 ]
Li, Pengcheng [1 ,2 ]
Cheng, Yanxiang [1 ]
Xie, Zhiyuan [1 ]
Wang, Lixiang [1 ]
Jing, Xiabin [1 ]
Wang, Fosong [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
LIGHT-EMITTING-DIODES; EFFICIENT; EMISSION; LUMINESCENCE; PERFORMANCE; MOLECULES;
D O I
10.1002/adma.201100297
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By incorporating six blue emissive polyfluorene arms into star-shaped orange emissive cores, two kinds of star-like white electroluminescent single-polymer systems are designed and synthesized. Energy transfer from the polyfluorene arms to the orange emissive cores is observed and a concentration quenching effect is effectively suppressed. Through thermal annealing, a highly efficient white emissive single-layer device is achieved with CIE coordinates of (0.33, 0.35) and a current efficiency of 18.01 cd A(-1).
引用
收藏
页码:2986 / +
页数:6
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