Nearly perfect triplet-triplet energy transfer from wannier excitons to naphthalene in organic-inorganic hybrid quantum-well materials

被引:186
作者
Ema, K. [1 ]
Inomata, M. [1 ]
Kato, Y. [1 ]
Kunugita, H. [1 ]
机构
[1] Sophia Univ, Dept Phys, Chiyoda Ku, Tokyo 1028554, Japan
关键词
D O I
10.1103/PhysRevLett.100.257401
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We report the observation of extremely efficient energy transfer (greater than 99%) in an organic-inorganic hybrid quantum-well structure consisting of perovskite-type lead bromide well layers and naphthalene-linked ammonium barrier layers. Time-resolved photoluminescence measurements confirm that the transfer is triplet-triplet Dexter-type energy transfer from Wannier excitons in the inorganic well to the triplet state of naphthalene molecules in the organic barrier. Using measurements in the 10-300 K temperature range, we also investigated the temperature dependence of the energy transfer.
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页数:4
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共 18 条
[1]   HYBRID INTERFACE EXCITONS IN ORGANIC-INORGANIC QUANTUM-WELLS [J].
AGRANOVICH, V ;
ATANASOV, R ;
BASSANI, F .
SOLID STATE COMMUNICATIONS, 1994, 92 (04) :295-301
[2]   Excitons and optical nonlinearities in hybrid organic-inorganic nanostructures [J].
Agranovich, VM ;
Basko, DM ;
La Rocca, GC ;
Bassani, F .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1998, 10 (42) :9369-9400
[3]   Excitons in hybrid organic-inorganic nanostructures [J].
Bassani, F ;
La Rocca, GC ;
Basko, DM ;
Agranovich, VM .
PHYSICS OF THE SOLID STATE, 1999, 41 (05) :701-703
[4]   Converting Wannier into Frenkel excitons in an inorganic/organic hybrid semiconductor nanostructure [J].
Blumstengel, S. ;
Sadofev, S. ;
Xu, C. ;
Puls, J. ;
Henneberger, F. .
PHYSICAL REVIEW LETTERS, 2006, 97 (23)
[5]   A THEORY OF SENSITIZED LUMINESCENCE IN SOLIDS [J].
DEXTER, DL .
JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (05) :836-850
[6]   Huge exchange energy and fine structure of excitons in an organic-inorganic quantum well material [J].
Ema, K. ;
Umeda, K. ;
Toda, M. ;
Yajima, C. ;
Arai, Y. ;
Kunugita, H. ;
Wolverson, D. ;
Davies, J. J. .
PHYSICAL REVIEW B, 2006, 73 (24)
[7]   Enhanced phosphorescence from naphthalene-chromophore incorporated into lead bromide-based layered perovskite having organic-inorganic superlattice structure [J].
Era, M ;
Maeda, K ;
Tsutsui, T .
CHEMICAL PHYSICS LETTERS, 1998, 296 (3-4) :417-420
[8]   *ZWISCHENMOLEKULARE ENERGIEWANDERUNG UND FLUORESZENZ [J].
FORSTER, T .
ANNALEN DER PHYSIK, 1948, 2 (1-2) :55-75
[9]   Tunable polariton absorption of distributed feedback microcavities at room temperature [J].
Fujita, T ;
Sato, Y ;
Kuitani, T ;
Ishihara, T .
PHYSICAL REVIEW B, 1998, 57 (19) :12428-12434
[10]   Time-to-space conversion of Tbits/s optical pulses using a self-organized quantum-well material [J].
Ishi, J ;
Kunugita, H ;
Ema, K ;
Ban, T ;
Kondo, T .
APPLIED PHYSICS LETTERS, 2000, 77 (22) :3487-3489