Effects of halide ligands and protic additives on enantioselectivity and reactivity in rhodium-catalyzed asymmetric ring-opening reactions

被引：110

作者：

Lautens, M ^{[1
]}

Fagnou, K ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Davenport Res Labs, Toronto, ON M5H 3H6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2001年 / 123卷 / 29期

关键词：

D O I：

10.1021/ja010262g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

No abstract available

引用

页码：7170 / 7171

页数：2

共 18 条

[1]

Blaser HU, 1999, SYNLETT, P867

[2] ASYMMETRIC ALLYLIC ALKYLATION WITH PALLADIUM COORDINATED TO A NEW OPTICALLY-ACTIVE PYRAZOLYLMETHANE LIGAND [J].

BOVENS, M ;

TOGNI, A ;

VENANZI, LM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 451 (1-2) :C28-C31

[3] A remarkable anion effect on the enantioselectivity of the Pd-catalyzed allylic amination using ferrocenyl ligands [J].

Burckhardt, U ;

Baumann, M ;

Togni, A .

TETRAHEDRON-ASYMMETRY, 1997, 8 (01) :155-159

[4] The [IrCl(diphosphine)](2)/fluoride system. Developing catalytic asymmetric olefin hydroamination [J].

Dorta, R ;

Egli, P ;

Zurcher, F ;

Togni, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (44) :10857-10858

[5] C-2-SYMMETRIC CATIONIC COPPER(II) COMPLEXES AS CHIRAL LEWIS-ACIDS - COUNTERION EFFECTS IN THE ENANTIOSELECTIVE DIELS-ALDER REACTION [J].

EVANS, DA ;

MURRY, JA ;

VONMATT, P ;

NORCROSS, RD ;

MILLER, SJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :798-800

[6] Rhodium-catalyzed ring opening of vinyl epoxides with alcohols and aromatic amines [J].

Fagnou, K ;

Lautens, M .

ORGANIC LETTERS, 2000, 2 (15) :2319-2321

[7]

FAGNOU K, IN PRESS ANGEW CHEM

[8] RHODIUM(I)-CATALYZED ASYMMETRIC HYDROGENATION OF IMINES [J].

KANG, GJ ;

CULLEN, WR ;

FRYZUK, MD ;

JAMES, BR ;

KUTNEY, JP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (22) :1466-1467

[9] Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with phenols [J].

Lautens, M ;

Fagnou, K ;

Taylor, M .

ORGANIC LETTERS, 2000, 2 (12) :1677-1679

[10] Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene: A new enantioselective carbon-heteroatom bond forming process [J].

Lautens, M ;

Fagnou, K ;

Rovis, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (23) :5650-5651

← 1 2 →