Spirocyclic [1]ferrocenophanes: Novel cross-linking agents for ring-opened poly(ferrocenes)

被引：38

作者：

MacLachlan, MJ ^{[1
]}

Lough, AJ ^{[1
]}

Manners, I ^{[1
]}

机构：

[1] UNIV TORONTO, DEPT CHEM, TORONTO, ON M5S 3H6, CANADA

来源：

MACROMOLECULES | 1996年 / 29卷 / 26期

关键词：

D O I：

10.1021/ma961260x

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Spirocyclic ferrocenophanes functions are convenient crosslinking agents for poly(ferrocenes) via thermal ring opening copolymerization reactions. The resulting polymers were characterized by differential scanning calorimetry (DSC) and their crosslinked nature was probed by swelling experiments using tetrahydrofuran (THF) as solvent. The resulting material was completely insoluble in THF and did not swell, which is consistent with the formation of highly crosslinked polymer. Furthermore, the material formed was amorphous by wide angle X-ray scattering.

引用

页码：8562 / 8564

页数：3

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