Stereodifferentiation in the Compartmentalized Photooxidation of a Protein-Bound Anthracene

被引：12

作者：

Alonso, Rafael ^{[1
]}

Consuelo Jimenez, M. ^{[1
]}

Miranda, Miguel A. ^{[1
]}

机构：

[1] Univ Politecn Valencia, Dept Quim, Inst Tecnol Quim UPV CSIC, E-46022 Valencia, Spain

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 15期

关键词：

TRANSIENT ABSORPTION-SPECTROSCOPY; HUMAN ALPHA(1)-ACID GLYCOPROTEIN; ANTI-MARKOVNIKOV PHOTOADDITION; TRIPLET EXCITED-STATE; ENANTIODIFFERENTIATING PHOTOCYCLODIMERIZATION; SUPRAMOLECULAR PHOTOCHIROGENESIS; SINGLET OXYGEN; SERUM-ALBUMIN; ASYMMETRIC PHOTOCHEMISTRY; GAMMA-CYCLODEXTRINS;

D O I：

10.1021/ol201209h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Encapsulation within transport proteins strongly reduces the photooxidation rate of (S)- and (R)-2-(9-anthracenyl)propanoic acid (1) and results in a significant stereodifferentiation. The most remarkable effects are observed within human serum albumin (HSA).

引用

页码：3860 / 3863

页数：4

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