The synthesis and evaluation of new α-hydrogen nitroxides for 'Living' free radical polymerization

被引：20

作者：

Braslau, R ^{[1
]}

O'Bryan, G ^{[1
]}

Nilsen, A ^{[1
]}

Henise, J ^{[1
]}

Thongpaisanwong, T ^{[1
]}

Murphy, E ^{[1
]}

Mueller, L ^{[1
]}

Ruehl, J ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

来源：

SYNTHESIS-STUTTGART | 2005年 / 09期

关键词：

nitroxide; nitrone; free radicals; polymers; Grignard reaction;

D O I：

10.1055/s-2005-869894

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three N-alkoxyamines were synthesized for use in nitroxide-mediated radical polymerization. Upon thermolysis, they generate new acyclic a-hydrogen nitroxides: one adamantyl substituted and two diol-containing nitroxides. The initiators were tested in polymerization reactions in direct comparison with the initiator derived from the nitroxide TIPNO.

引用

页码：1496 / 1506

页数：11

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