CNx nanotubes as catalyst support to immobilize platinum nanoparticles for methanol oxidation

被引：172

作者：

Yue, Bing ^{[1
,4
]}

Ma, Yanwen ^{[1
,4
]}

Tao, Haisheng ^{[1
,4
]}

Yu, Leshu ^{[1
,4
]}

Jian, Guoqiang ^{[1
,4
]}

Wang, Xizhang ^{[1
,4
]}

Wang, Xiaoshu ^{[2
]}

Lu, Yinong ^{[3
]}

Hu, Zheng ^{[1
,4
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Jiangsu Prov Lab Nanotechnol, Nanjing 210093, Peoples R China

[2] Nanjing Univ, Ctr Mat Anal, Nanjing 210093, Peoples R China

[3] Nanjing Univ Technol, Coll Mat Sci & Engn, Nanjing 210009, Peoples R China

[4] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem MOE, Nanjing 210093, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2008年 / 18卷 / 15期

关键词：

D O I：

10.1039/b718283j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pt nanoparticles with sizes of 3-9 nm were well dispersed on carbon nitride (CNx) nanotubes without needing pre-surface modification on the CNx nanotubes due to the inherent chemical activity. The products were characterized by transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy. All the experimental results revealed that Pt nanoparticles were immobilized on the CNx nanotubes due to the N-participation in the connection of Pt species with the support. The electrocatalytic property of the as-prepared Pt/CNx catalyst in methanol oxidation was examined by cyclic voltammetry. The results reveal that the so-constructed Pt/CNx catalyst has obvious catalytic activity, suggesting potential applications in fuel cells.

引用

页码：1747 / 1750

页数：4

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