Investigation of LIBS feasibility for in situ planetary exploration:: An analysis on Martian rock analogues

被引:174
作者
Colao, F
Fantoni, R
Lazic, V
Paolini, A
Fabbri, F
Ori, GG
Marinangeli, L
Baliva, A
机构
[1] LAS, Dept FIS, ENEA, I-00044 Frascati, RM, Italy
[2] Univ G dAnnunzio, IRSPS, Pescara, Italy
关键词
LIBS; terrestrial analogues; mars; silicate minerals;
D O I
10.1016/j.pss.2003.08.012
中图分类号
P1 [天文学];
学科分类号
0704 ;
摘要
Laser induced breakdown spectroscopy (LIBS) has significant potential for remote terrestrial and extraterrestrial applications, nonetheless a number of correlated problems are still to be properly understood and possibly solved. This study focuses on several samples of terrestrial provenience, mostly volcanic rocks, which have importance as analogue to expected Martian samples. They were analysed after vaporisation with a frequency tripled Nd:YAG laser emitting at 355 nm, and measurements were made in an environment similar to the Martian one. Quantitative data were obtained by adopting the calibration free LIBS approach. A comparison with SEM-EDX data from the same samples is reported. Present results on Mars rocks analogues suggest that, in spite of residual interpretative ambiguities, LIBS technique permits elemental qualitative identification and quantitative analysis on silicate minerals examined in a rarefied atmosphere. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:117 / 123
页数:7
相关论文
共 19 条
[1]   Temperature and electron density distributions of laser-induced plasmas generated with an iron sample at different ambient gas pressures [J].
Aguilera, JA ;
Aragón, C .
APPLIED SURFACE SCIENCE, 2002, 197 :273-280
[2]   Influence of the optical depth on spectral line emission from laser-induced plasmas [J].
Aragón, C ;
Bengoechea, J ;
Aguilera, JA .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2001, 56 (06) :619-628
[3]   Analysis of soil and sediment samples by laser ablation inductively coupled plasma mass spectrometry [J].
Baker, SA ;
Bi, M ;
Aucelio, RQ ;
Smith, BW ;
Winefordner, JD .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1999, 14 (01) :19-26
[4]   A global view of Martian surface compositions from MGS-TES [J].
Bandfield, JL ;
Hamilton, VE ;
Christensen, PR .
SCIENCE, 2000, 287 (5458) :1626-1630
[5]   Semi-quantitative time resolved LIBS measurements [J].
Barbini, R ;
Colao, F ;
Fantoni, R ;
Palucci, A ;
Ribezzo, S ;
vanderSteen, HJL ;
Angelone, M .
APPLIED PHYSICS B-LASERS AND OPTICS, 1997, 65 (01) :101-107
[6]  
Barbini R, 1999, APPL PHYS A-MATER, V69, pS175
[7]   A procedure for correcting self-absorption in calibration free-laser induced breakdown spectroscopy [J].
Bulajic, D ;
Corsi, M ;
Cristoforetti, G ;
Legnaioli, S ;
Palleschi, V ;
Salvetti, A ;
Tognoni, E .
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2002, 57 (02) :339-353
[8]   Study of matrix effects in laser plasma spectroscopy by combined multifiber spatial and temporal resolutions [J].
Bulatov, V ;
Krasniker, R ;
Schechter, I .
ANALYTICAL CHEMISTRY, 1998, 70 (24) :5302-5311
[9]   Variables influencing the precision of laser-induced breakdown spectroscopy measurements [J].
Castle, BC ;
Talabardon, K ;
Smith, BW ;
Winefordner, JD .
APPLIED SPECTROSCOPY, 1998, 52 (05) :649-657
[10]   Trace pollutants analysis in soil by a time-resolved laser-induced breakdown spectroscopy technique [J].
Ciucci, A ;
Palleschi, V ;
Rastelli, S ;
Barbini, R ;
Colao, F ;
Fantoni, R ;
Palucci, A ;
Ribezzo, S ;
vanderSteen, HJL .
APPLIED PHYSICS B-LASERS AND OPTICS, 1996, 63 (02) :185-190