Sol-gel preparation of Ti1-xVxO2 solid solution film electrodes with conspicuous photoresponse in the visible region

被引：88

作者：

Zhao, GL

Kozuka, H

Lin, H

Yoko, T ^{[1
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Uji, Kyoto 611, Japan

[2] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China

来源：

THIN SOLID FILMS | 1999年 / 339卷 / 1-2期

关键词：

titanium oxide; vanadium oxide; solid solution; photoelectrochemistry; sol-gel film;

D O I：

10.1016/S0040-6090(98)01227-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Titanium-vanadium oxide films have been prepared by the sol-gel method using a starting solution containing titanium isopropoxide and vanadium(IV) oxyacetyl acetonate. Solid solubility of VO2 in TiO2 matrix and the effects of vanadium incorporation on the crystallization behavior of TiO2 were investigated by an X-ray diffraction analysis. It was found that the absorption edge of Ti1-xVxO2 films shifted to longer wavelengths when x increased. The sol-gel derived Ti0.95V0.05O2 film electrode was found to exhibit a conspicuous photoresponse in the visible region. Moreover, this film electrode was proved to be photoelectrochemically quite stable. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：123 / 128

页数：6

共 21 条

[1] Barrer R.M., 1941, Diffusion in and Through Solids
[2] PHASE-TRANSFORMATION OF TITANIUM-DIOXIDE IN THE PREPARATION OF TITANIUM-OXIDE VANADIUM-OXIDE ELECTRODES FOR COMPLEXOMETRIC TITRATION
BEHRENS, R
UMLAND, F
[J]. JOURNAL OF THE LESS-COMMON METALS, 1988, 137 (1-2): : 353 - 365
[3] TEMPERATURE-INDUCED DIFFUSION OF PROBE VANADIUM(IV) IONS INTO THE MATRIX OF TITANIUM-DIOXIDE AS INVESTIGATED BY ESR TECHNIQUES
DAVIDSON, A
CHE, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (24) : 9909 - 9915
[4] MICROSTRUCTURAL STUDY OF VANADIUM-TITANIUM OXIDE POWDERS OBTAINED BY LASER-INDUCED SYNTHESIS
DEPERO, LE
BONZI, P
MUSCI, M
CASALE, C
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1994, 111 (02) : 247 - 252
[5] Gratzel M, 1991, NATURE, V353, P737, DOI DOI 10.1038/53737A0
[6] HUCKNALL DJ, 1974, SELECTIVE OXIDATION, P152
[7] ON THE DEFECT STRUCTURE OF RUTILE
HURLEN, T
[J]. ACTA CHEMICA SCANDINAVICA, 1959, 13 (02): : 365 - 376
[8] KRISHNA KM, 1992, CHEM PHYS, V163, P401
[9] SEMICONDUCTOR-TO-SEMICONDUCTOR TRANSITION IN PSEUDOBINARY SYSTEM TIO2-VO2
KRISTENSEN, IK
[J]. JOURNAL OF APPLIED PHYSICS, 1968, 39 (11) : 5341 - +
[10] VANADIUM AND TITANIUM-OXIDES PREPARED BY HYDROLYSIS OF ALKOXIDES AS INSERTION ELECTRODES IN LITHIUM CELLS WITH POLYMERIC ELECTROLYTES
MINETT, MG
OWEN, JR
[J]. JOURNAL OF POWER SOURCES, 1990, 32 (01) : 81 - 97

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