Structural and spectral studies of di-2-pyridyl ketone N(4)-methyl- and N(4)-dimethylthiosemicarbazone and their metal complexes

被引：54

作者：

Swearingen, JK ^{[1
]}

West, DX ^{[1
]}

机构：

[1] Illinois State Univ, Dept Chem, Normal, IL 61790 USA

来源：

TRANSITION METAL CHEMISTRY | 2001年 / 26卷 / 03期

关键词：

D O I：

10.1023/A:1007139022915

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cobalt(II), nickel(II) and copper(II) complexes of di-2-pyridyl ketone N(4)-methyl- and N(4)-dimethylthiosemicarbazone have been prepared and characterized by physical and spectral methods. Use of different ligand-to-metal chloride molar ratios in the preparation of the complexes has produced both mononuclear and polynuclear species for the three metal ions. Crystal structures of the uncomplexed di-2-pyridyl ketone N(4)-methylthiosemicarbazone and a nickel(II) complex, di-2-pyridyl ketone N(4)-dimethylthiosemicarbazone, have been determined and aid the assignments of the i.r., n.m.r., u.v.-vis.-n.i.r. and e.s.r. spectra.

引用

页码：252 / 260

页数：9

共 37 条

[1] STOICHIOMETRIC, STRUCTURAL AND THERMAL INVESTIGATIONS ON CU(II), NI(II) AND CO(II) COORDINATION-COMPOUNDS OF SOME ACID HYDRAZIDE BASES [J].

AGRAWAL, SK ;

TUTLANI, DR ;

GUPTA, R ;

HAJELA, SK .

INORGANICA CHIMICA ACTA, 1987, 129 (02) :257-259

[2] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[3]

Beraldo H, 1998, TRANSIT METAL CHEM, V23, P67

[4] Copper(II) and nickel(II) complexes of pyruvaldehyde bis{N(3)-substituted thiosemicarbazones} [J].

Beraldo, H ;

West, DX .

TRANSITION METAL CHEMISTRY, 1997, 22 (03) :294-298

[5] Copper(II) and nickel(II) complexes of the bis{N(3)-substituted thiosemicarbazones} of phenylglyoxal and 1-phenylpropane-1,2-dione [J].

Beraldo, H ;

Kaisner, SB ;

Turner, JD ;

Billeh, IS ;

Ives, JS ;

West, DX .

TRANSITION METAL CHEMISTRY, 1997, 22 (05) :459-464

[6] COMPLEXES OF COBALT(II), NICKEL(II) AND COPPER(II) WITH 4-AMINO-3,5-DIMETHYLISOXAZOLE [J].

BIDDAU, M ;

MASSACESI, M ;

PINNA, R ;

PONTICELLI, G .

TRANSITION METAL CHEMISTRY, 1978, 3 (03) :153-156

[7]

BYUSHKIN VN, 1987, ZH STRUKT KHIM, V28, P140

[8] Spectral and structural studies of metal complexes of 1-phenylglyoxal bis{N(3)-diethylthiosemicarbazone} [J].

Castineiras, A ;

Bermejo, E ;

West, DX ;

El-Sawaf, AK ;

Swearingen, JK .

POLYHEDRON, 1998, 17 (16) :2751-2757

[9] Structural and spectral studies of 1-phenylglyoxal bis(3-piperidylthiosemicarbazone) and its zinc(II), cadmium(II) and platinum(II) complexes [J].

Castiñeiras, A ;

Bermejo, E ;

West, DX ;

Ackerman, LJ ;

Valdés-Martínez, J ;

Hernández-Ortega, S .

POLYHEDRON, 1999, 18 (10) :1463-1469

[10]

CASTINEIRAS A, UNPUB

← 1 2 3 4 →