A novel one-dimensional structure involving mu(4)-TCNQ ligands and quadruply bonded dimolybdenum units (TCNQ equals 7,7,8,8-tetracyanoquinodimethane)

被引：46

作者：

Campana, C

Dunbar, KR

Ouyang, X

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

[2] MICHIGAN STATE UNIV,CTR FUNDAMENTAL MAT RES,E LANSING,MI 48824

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 21期

关键词：

D O I：

10.1039/cc9960002427

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Mo-2(O2CCF3)(4) with TCNQ (TCNQ = 7,7,8,8-tetracyanoquinodimethane) in xylenes yields [Mo-2(O2CCF3)(4)(TCNQ)(0.5). m-xylene](2) .[MO(2)(O2CCF3)(4) .(m-xylene)] 1, an unprecedented one-dimensional mu(4)-TCNQ polymer, which is characterized by X-ray crystallography.

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页码：2427 / 2428

页数：2

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