Syntheses, structures and luminescent properties of new lanthanide-based coordination polymers based on 1,4-benzenedicarboxylate (bdc)

被引：70

作者：

Yang, Xiao-Ping ^{[1
]}

Jones, Richard A. ^{[1
]}

Rivers, Joseph H. ^{[1
]}

Lai, Rachel Pen-Jen ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

DALTON TRANSACTIONS | 2007年 / 35期

关键词：

D O I：

10.1039/b706823a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 1,4-benzenedicarboxylic acid (1,4-H2BDC) with EUCl3 center dot 6H(2)O in MeOH in the presence of Et3N and MeCN gives a mixture of the 3-D metal-organic-framework (MOF) materials [Eu-2(1,4-BDC)(3)(MeOH)(4)]center dot 8MeOH (1) and 2-D [Eu(1,4-BDC)(MeOH)(4)]center dot Cl center dot MeOH center dot 0.25H(2)O (2). Similar reactions afforded the isomorphous Gd (3) and Tb (4) analogs of 2. Reaction of 1,4-H2BDC with Ln(NO3)(3).6H(2)O under similar conditions gave [Ln(BDC)NO3(MeOH)(2)]center dot MeCN center dot H2O (Ln = Eu (5) and Cid (6)), which have 2-D framework structures. The structures of 1-6 were determined by single crystal X-ray crystallographic studies and the luminescence properties of I and 4 in DMF solution were determined.

引用

页码：3936 / 3942

页数：7

共 46 条

[1] Syntheses and characterizations of three-dimensional channel-like polymeric lanthanide complexes constructed by 1,2,4,5-benzenetetracarboxylic acid [J].

Cao, R ;

Sun, DF ;

Liang, YC ;

Hong, MC ;

Tatsumi, K ;

Shi, Q .

INORGANIC CHEMISTRY, 2002, 41 (08) :2087-2094

[2] NEW SERIES OF ANHYDROUS DOUBLE NITRATE SALTS OF LANTHANIDES - STRUCTURAL AND SPECTRAL CHARACTERIZATION [J].

CARNALL, WT ;

SIEGEL, S ;

FERRARO, JR ;

TANI, B ;

GEBERT, E .

INORGANIC CHEMISTRY, 1973, 12 (03) :560-564

[3]

Champness NR, 2006, DALTON T, P877, DOI 10.1039/b512638j

[4]

COTTON FA, 1988, ADV INORG CHEM RAD, P840

[5]

CROMER DT, 1974, INT TABLES XRAY CRYS, V4, P2

[6] Synthesis and crystal structure of two new rare earth trimesate complexes:: ErTMA(H2O)5•3.5H2O and YTMA(H2O)6 [J].

Daiguebonne, C ;

Guilloa, O ;

Gérault, Y ;

Lecerf, A ;

Boubekeur, K .

INORGANICA CHIMICA ACTA, 1999, 284 (01) :139-145

[7] Synthesis, crystal structure of a new tridimensional family of materials:: LnCHA(H2O)2•2.5H2O (Ln = Dy-Yb) [J].

Daiguebonne, C ;

Guillou, O ;

Gérault, Y ;

Boubekeur, K .

JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 323 :199-203

[8] Interplane distances modulation in lanthanide-based coordination polymers [J].

Deluzet, A ;

Maudez, W ;

Daiguebonne, C ;

Guillou, O .

CRYSTAL GROWTH & DESIGN, 2003, 3 (04) :475-479

[9]

Evans OR, 1999, ANGEW CHEM INT EDIT, V38, P536, DOI 10.1002/(SICI)1521-3773(19990215)38:4<536::AID-ANIE536>3.0.CO

[10]

2-3

← 1 2 3 4 5 →