Biotransformation of allylically activated (E,E)-cyclodeca-1,6-dienols by Cichorium intybus

被引：9

作者：

Piet, DP ^{[1
]}

Franssen, MCR ^{[1
]}

deGroot, A ^{[1
]}

机构：

[1] AGR UNIV WAGENINGEN,DEPT ORGAN CHEM,NL-6703 HB WAGENINGEN,NETHERLANDS

来源：

TETRAHEDRON | 1996年 / 52卷 / 34期

关键词：

D O I：

10.1016/0040-4020(96)00653-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The biotransformation of (E,E)-cyclodeca-1,6-dienols 2a-c by a root suspension of fresh chicory (Cichorium intybus) is described. Incubation of 2a-c gave mixtures of products arising from 1.5- or 1,7-cyclisation (3a-c and 4a-c, respectively). An explanation for the obtained results is proposed together with a new biosynthetic route for the bitter principles in chicory. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：11273 / 11280

页数：8

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