Control of coordination chemistry in both the framework and the pore channels of mesoporous hybrid materials

被引：60

作者：

Corriu, RJP ^{[1
]}

Mehdi, A ^{[1
]}

Reyé, C ^{[1
]}

Thieuleux, C ^{[1
]}

机构：

[1] Univ Montpellier 2, CNRS, UMR 5637, Lab Chim Mol & Org Solide, F-34095 Montpellier 5, France

来源：

NEW JOURNAL OF CHEMISTRY | 2003年 / 27卷 / 06期

关键词：

D O I：

10.1039/b302027d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mesoporous materials containing bridged cyclam moieties inside the framework were prepared by using a neutral templating route. Quantitative formation of bridged Cu-II-cyclam complexes was obtained by the direct incorporation of CuCl2 inside the hybrid material, showing thus the complete accessibility of cyclam moieties located inside the framework. Grafting of a metal-N-triethoxysilylpropylcyclam complex inside the channel pores followed by the incorporation of another metal salt into the framework gave rise to an hybrid material containing two strongly chelated metal salts, one located inside the framework, the other in the channel pores.

引用

页码：905 / 908

页数：4

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