Synthesis of palladium(II) and platinum(II) complexes with crown ether phosphane ligands:: Stille coupling of aryl iodides in water

被引：16

作者：

Fresneda, J ^{[1
]}

de Jesús, E ^{[1
]}

Gómez-Sal, P ^{[1
]}

Mardomingo, CL ^{[1
]}

机构：

[1] Univ Alcala de Henares, Dept Quim Organ, Madrid 28871, Spain

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 08期

关键词：

aqueous-phase catalysis; crown compounds; C-C coupling; palladium; phosphane ligands;

D O I：

10.1002/ejic.200400906

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crown ether phosphanes (PArPh2)-Ph-* (1) and PAr(*)2R [Ar-* = 3,4-(18-crown-6)-phenyl; R = Me (2); R = Ph (3)], prepared from PCl2R and (ArLi)-Li-*, have been studied. The syntheses and characterization of their oxides (4-6), and their BH3 (7-9), PdCl2 (10-12), and PtCl2 (13-15) complexes are reported. The molecular structure of the borane complex (PAr2PhBH3)-Ph-*-B-. (9) has been determined by X-ray structural analysis. Spectroscopic data suggest that phosphanes 1-3 have similar electronic properties and steric requirements to the corresponding phenylphosphane ligands PPh2Me and PPh3. Crown ether methylphosphane 2 and its complexes are remarkably water soluble, but 1 and 3 are only slightly soluble. Palladium(II) complexes 14 and 15 have been tested as catalysts in the Stille coupling of phenyltrichlorostannanes and aryl iodides in water. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).

引用

页码：1468 / 1476

页数：9

共 45 条

[1] STRUCTURAL STUDIES OF STERIC EFFECTS IN PHOSPHINE COMPLEXES - SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF DINITRATO(TRICYCLOHEXYLPHOSPHINE)MERCURY(II) DIMER [J].

ALYEA, EC ;

DIAS, SA ;

FERGUSON, G ;

RESTIVO, RJ .

INORGANIC CHEMISTRY, 1977, 16 (09) :2329-2334

[2] REACTIVITY OF PLATINUM DIOLEFIN COMPLEXES .2. REACTIONS WITH BULKY AND CHELATING GROUP-5B LIGANDS AND STUDIES RELATING TO CARBONYL INSERTION [J].

ANDERSON, GK ;

CLARK, HC ;

DAVIES, JA .

INORGANIC CHEMISTRY, 1981, 20 (11) :3607-3611

[3]

[Anonymous], AQUEOUS PHASE ORGANO

[4] Phosphines functionalized with crown ether groups: Synthesis and study of systems incorporating 1,3-xylyl-18-crown-5 units [J].

Barg, LA ;

Byrn, RW ;

Carr, MD ;

Nolan, DH ;

Storhoff, BN ;

Huffman, JC .

ORGANOMETALLICS, 1998, 17 (07) :1340-1346

[5] DETERMINATION OF SPATIAL FULFILLMENT OF TERTIARY PHOSPHANES ON P-31 NMR SPECTROSCOPIC DATA OF TRANS-L2PDCL2- COMPLEXES [J].

BARTIK, T ;

HIMMLER, T .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 293 (03) :343-351

[6] WATER-SOLUBLE ELECTRON-DONATING PHOSPHINES - SULFONATION OF TRIS(OMEGA-PHENYLALKYL)PHOSPHINES [J].

BARTIK, T ;

BARTIK, B ;

HANSON, BE ;

GUO, I ;

TOTH, I .

ORGANOMETALLICS, 1993, 12 (01) :164-170

[7] STUDIES OF PHOSPHORUS(III) LIGANDS AND THEIR COMPLEXES OF NI(II), PD(II), AND PT(II) IMMOBILIZED ON INSOLUBLE SUPPORTS BY HIGH-RESOLUTION SOLID-STATE P-31 NMR USING MAGIC-ANGLE SPINNING TECHNIQUES [J].

BEMI, L ;

CLARK, HC ;

DAVIES, JA ;

FYFE, CA ;

WASYLISHEN, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (02) :438-445

[8] Metal ion complexation in organometallic crown ethers - Structural and rate effects on the migratory insertion of carbon monoxide in indenyl and cyclopentadienyl iron (II) complexes [J].

Berdini, V ;

Bassetti, M ;

Mancini, G ;

Mandolini, L ;

Monti, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 551 (1-2) :331-338

[9] PHOSPHINE-BORANE COMPLEXES - DIRECT USE IN ASYMMETRIC CATALYSIS [J].

BRISSET, H ;

GOURDEL, Y ;

PELLON, P ;

LECORRE, M .

TETRAHEDRON LETTERS, 1993, 34 (28) :4523-4526

[10]

Cornils B., 2004, Aqueous-Phase Organometallic Catalysis: Concepts and Applications

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