Removal of chromium from aqueous solution by complexation - Ultrafiltration using a water-soluble macroligand

被引:67
作者
Aliane, A
Bounatiro, N
Cherif, AT
Akretche, DE
机构
[1] Ctr Dev Mat, Lab Anal & Traitement Effluents, Draria, Algeria
[2] USTHB, Lab Valorisat Minerais, El Alia, Algeria
关键词
ultrafiltration; complexation; ligand-chromium;
D O I
10.1016/S0043-1354(00)00501-7
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A process for purifying waste waters containing heavy and toxic metal such as chromium has been studied. A batch complexation-ultrafiltration process was used to concentrate and recover chromium from sulphate solution. As the chromium ions cli e tao small to be retained by the filter, they are fil st complexed with a water-soluble macroligand (polyethylene-imine), Factors affecting the rejection late and permeate flux such as pH, concentration ligand. chloride and sulphate concentration, membrane pore size, applied pressure and extraction factor were investigated. Best operating conditions can be obtained in order to achieve high levels of removal (>95%). Then, decomplexation is obtained so that metal can be separated from macroligand by second ultrafiltration plant to reuse the macroligand. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2320 / 2326
页数:7
相关论文
共 20 条
[1]  
AULAS F, 1980, ACTUAL CHIMIQUE, V6, P13
[2]  
BEMBERIS I, 1986, CHEM ENG PROG, V82, P29
[3]  
BERTORELLA E, 1976, GALVANOTECNICA, V27, P155
[4]  
BULBULA A, 1975, AICHE J S SCI, V71, P105
[5]  
CHERYAN M, 1986, ULTRAFILTRATION HDB
[6]   REMOVAL OF HEAVY-METALS FROM ELECTROPLATING RINSEWATERS BY PRECIPITATION, FLOCCULATION AND ULTRAFILTRATION [J].
CHRISTENSEN, ER ;
DELWICHE, JT .
WATER RESEARCH, 1982, 16 (05) :729-737
[7]  
GECKLER K, 1980, PURE APPL CHEM, V52, P1983
[8]   ULTRAFILTRATION APPLICATIONS [J].
JONSSON, AS ;
TRAGARDH, G .
DESALINATION, 1990, 77 (1-3) :135-179
[9]   EQUILIBRIUM STUDIES FOR THE INTERACTION OF AQUEOUS METAL-IONS AND POLYACRYLIC-ACID BY A BATCH ULTRAFILTRATION METHOD [J].
JUANG, RS ;
LIANG, JF .
JOURNAL OF MEMBRANE SCIENCE, 1993, 82 (1-2) :163-174
[10]  
KORTLY S, 1985, HDB CHEM EQUILIBRIA