Anion and cation interactions with p-dodecanoylcalix[4]arene monolayers at the air-water interface

被引:33
作者
Shahgaldian, P [1 ]
Coleman, AW [1 ]
机构
[1] Inst Biol Chim Prot, CNRS UMR 5086, F-69367 Lyon 07, France
关键词
D O I
10.1021/la010562b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Langmuir compression isotherms of p-dodecanoylcalix[4]arene have been studied on subphases containing varying concentrations of group IA salts. The effect of anions on the stability of the monolayers shows that, for acetate and bicarbonate, there is a large increase in collapse pressure, when sodium is the countercation. In the case of cation effects, rubidium chloride shows a large stabilization of the monolayer.
引用
收藏
页码:6851 / 6854
页数:4
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