Nanotexture Switching of Single-Layer Hexagonal Boron Nitride on Rhodium by Intercalation of Hydrogen Atoms

被引：68

作者：

Brugger, Thomas ^{[1
]}

Ma, Haifeng ^{[1
]}

Iannuzzi, Marcella ^{[2
]}

Berner, Simon ^{[1
]}

Winkler, Adolf ^{[3
]}

Hutter, Juerg ^{[2
]}

Osterwalder, Juerg ^{[1
]}

Greber, Thomas ^{[1
]}

机构：

[1] Univ Zurich, Inst Phys, CH-8057 Zurich, Switzerland

[2] Univ Zurich, Inst Phys Chem, CH-8057 Zurich, Switzerland

[3] Graz Univ Technol, Inst Solid State Phys, A-8010 Graz, Austria

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 35期

基金：

瑞士国家科学基金会;

关键词：

intercalations; isotope effects; monolayers; nanostructures; rhodium; GRAPHITE;

D O I：

10.1002/anie.201001064

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Playing nano-tectonics: The interaction of atomic hydrogen with a single layer of hexagonal boron nitride on rhodium leads to the removal of the h-BN surface corrugation (see picture; blue region: corrugated, orange region: flat). This change of surface texture arises from the intercalation of hydrogen atoms between the h-BN skin and the metal, and can be restored by annealing to about 600 K to expel the hydrogen atoms. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6120 / 6124

页数：5

共 24 条

[1]

Berner S., 2007, Angew. Chem, V119, P5207, DOI [10.1002/ange.200700234, DOI 10.1002/ANGE.200700234]

[2] Boron nitride nanomesh: Functionality from a corrugated monolayer [J].

Berner, Simon ;

Corso, Martina ;

Widmer, Roland ;

Groening, Oliver ;

Laskowski, Robert ;

Blaha, Peter ;

Schwarz, Karlheinz ;

Goriachko, Andrii ;

Over, Herbert ;

Gsell, Stefan ;

Schreck, Matthias ;

Sachdev, Hermann ;

Greber, Thomas ;

Osterwalder, Juerg .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (27) :5115-5119

[3] Comparison of electronic structure and template function of single-layer graphene and a hexagonal boron nitride nanomesh on Ru(0001) [J].

Brugger, Thomas ;

Guenther, Sebastian ;

Wang, Bin ;

Dil, J. Hugo ;

Bocquet, Marie-Laure ;

Osterwalder, Juerg ;

Wintterlin, Joost ;

Greber, Thomas .

PHYSICAL REVIEW B, 2009, 79 (04)

[4] Boron nitride nanomesh [J].

Corso, M ;

Auwärter, W ;

Muntwiler, M ;

Tamai, A ;

Greber, T ;

Osterwalder, J .

SCIENCE, 2004, 303 (5655) :217-220

[5] Surface trapping of atoms and molecules with dipole rings [J].

Dil, Hugo ;

Lobo-Checa, Jorge ;

Laskowski, Robert ;

Blaha, Peter ;

Berner, Simon ;

Osterwalder, Juerg ;

Greber, Thomas .

SCIENCE, 2008, 319 (5871) :1824-1826

[6] INTERCALATION COMPOUNDS OF GRAPHITE [J].

DRESSELHAUS, MS ;

DRESSELHAUS, G .

ADVANCES IN PHYSICS, 1981, 30 (02) :139-326

[7] Quantitative characterization of a highly effective atomic hydrogen doser [J].

Eibl, C ;

Lackner, G ;

Winkler, A .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1998, 16 (05) :2979-2989

[8] Location of hydrogen adsorbed on Rh(111) studied by low-energy electron diffraction and nuclear reaction analysis [J].

Fukuoka, Masayuki ;

Okada, Michio ;

Matsumoto, Masuaki ;

Ogura, Shouhei ;

Fukutani, Katsuyuki ;

Kasai, Toshio .

PHYSICAL REVIEW B, 2007, 75 (23)

[9] Separable dual-space Gaussian pseudopotentials [J].

Goedecker, S ;

Teter, M ;

Hutter, J .

PHYSICAL REVIEW B, 1996, 54 (03) :1703-1710

[10] A photoelectron spectrometer for k-space mapping above the Fermi level [J].

Greber, T ;

Raetzo, O ;

Kreutz, TJ ;

Schwaller, P ;

Deichmann, W ;

Wetli, E ;

Osterwalder, J .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1997, 68 (12) :4549-4554

← 1 2 3 →