Asymmetric addition of diethylzinc to N-(diphenylphosphinoyl) imines

被引：38

作者：

Pinho, P ^{[1
]}

Andersson, PG ^{[1
]}

机构：

[1] Univ Uppsala, Inst Chem, Dept Organ Chem, S-75121 Uppsala, Sweden

来源：

TETRAHEDRON | 2001年 / 57卷 / 08期

关键词：

asymmetric additions; diethylzinc; amino alcohols; chiral auxiliaries;

D O I：

10.1016/S0040-4020(00)01142-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of dialkylzinc reagents to N-(diphenylphosphinoyl) imines is a convenient method for the preparation of optically enriched amines. Herein we present our most recent results on this reaction, including solvent effects on the enantioselectivity and the extension of this method to a variety of N-(diphenylphosphinoyl) imines. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1615 / 1618

页数：4

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