A Series of 3D Rare-Earth-Metal-Organic Frameworks with Isolated Guest Keggin Silicotungstate Fragments as Anion Templates

被引：18

作者：

Li, Suzhi ^{[1
,2
]}

Zhang, Dongdi ^{[1
]}

Guo, Yuanyuan ^{[1
]}

Ma, Pengtao ^{[1
]}

Zhao, Junwei ^{[1
]}

Wang, Jingping ^{[1
]}

Niu, Jingyang ^{[1
]}

机构：

[1] Henan Univ, Inst Mol & Crystal Engn, Coll Chem & Chem Engn, Kaifeng 475004, Henan, Peoples R China

[2] Shangqiu Normal Univ, Dept Chem, Shangqiu 476000, Henan, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 35期

基金：

中国国家自然科学基金;

关键词：

Silicotungstate; Polyoxometalates; Photoluminescence; Metal-organic frameworks; Rare earths; 3-DIMENSIONAL LANTHANIDE COMPLEXES; COORDINATION POLYMERS; HYBRID MATERIALS; CRYSTAL-STRUCTURES; SUPRAMOLECULAR ISOMERISM; HYDROTHERMAL SYNTHESIS; HYDROGEN STORAGE; OXIDE CHAINS; SOLID-STATE; IN-SITU;

D O I：

10.1002/ejic.201100944

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six rare-earth (RE) metal constructed 3D metalorganic frameworks, [RE(pydc)(H2O)n]4[SiW12O40]center dot 4H2O [RE = TmIII (1), YIII (2), PrIII (3), LaIII (4), SmIII (5), EuIII (6); n = 3 (1, 2), 4 (36); H2pydc = pyridine-2,6-dicarboxylic acid], have been synthesized and characterized by elemental analyses, inductively coupled plasma techniques, IR and UV spectroscopy, thermogravimetric analyses (for 1 and 3), X-ray powder diffraction, and single-crystal X-ray diffraction. The structural analyses indicate that 16 are basically isostructural and show a rare host 3D framework that contains [SiW12O40]4 Keggin polyoxoanions as templates. Photoluminescence measurements reveal that 15 show the luminescence of pydc ligands, whereas 6 displays a unique red luminescence.

引用

页码：5397 / 5404

页数：8

共 116 条

[1] Stress-induced Chemical Detection Using Flexible Metal-Organic Frameworks [J].