Q-band splitting and relaxation of aluminum phthalocyanine tetrasulfonate

被引：35

作者：

Reinot, T

Hayes, JM ^{[1
]}

Small, GJ

Zerner, MC

机构：

[1] Iowa State Univ, Ames Lab, US DOE, Ames, IA 50011 USA

[2] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

[3] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 299卷 / 05期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0009-2614(98)01346-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The doublet band structure evident in the fluorescence excitation and absorption spectra of aluminum phthalocyanine tetrasulfonate in various hyperquenched glassy solvents is attributed to splitting of the Q-band transition into x and y components. The splitting is caused by the ligation of water molecules to the aluminum atom which decreases the molecular symmetry. Picosecond relaxation from the Q(y) band to the Q(x) band is evident in the hole burned spectra. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：410 / 416

页数：7

相关论文

共 22 条

[1] INTERMEDIATE NEGLECT OF DIFFERENTIAL OVERLAP THEORY FOR TRANSITION-METAL COMPLEXES - FE, CO AND CU CHLORIDES [J].

BACON, AD ;

ZERNER, MC .

THEORETICA CHIMICA ACTA, 1979, 53 (01) :21-54

[2] Interpretation of multiple Q(0,0) bands in the absorption spectrum of Mg-mesoporphyrin embedded in horseradish peroxidase [J].

Balog, E ;

KisPetik, K ;

Fidy, J ;

Kohler, M ;

Friedrich, J .

BIOPHYSICAL JOURNAL, 1997, 73 (01) :397-405

[3] HIGH-RESOLUTION ZEEMAN EXPERIMENTS ON SINGLET, TRIPLET, AND QUARTET STATES OF METALLOPORPHINES [J].

CANTERS, GW ;

JANSEN, G ;

NOORT, M ;

VANDERWAALS, JH .

JOURNAL OF PHYSICAL CHEMISTRY, 1976, 80 (20) :2253-2259

[4] PHTHALOCYANINE FLUORESCENCE AT HIGH-CONCENTRATION - DIMERS OR REABSORPTION EFFECT [J].

DHAMI, S ;

DEMELLO, AJ ;

RUMBLES, G ;

BISHOP, SM ;

PHILLIPS, D ;

BEEBY, A .

PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1995, 61 (04) :341-346

[5] PORPHYRINS .15. VAPOR ABSORPTION SPECTRA AND STABILITY . PHTHALOCYANINES [J].

EDWARDS, L ;

GOUTERMAN, M .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1970, 33 (02) :292-+

[6] AN APPROXIMATE HESSIAN FOR MOLECULAR-GEOMETRY OPTIMIZATION [J].

HEAD, JD ;

ZERNER, MC .

CHEMICAL PHYSICS LETTERS, 1986, 131 (4-5) :359-366

[7] A BROYDEN-FLETCHER-GOLDFARB-SHANNO OPTIMIZATION PROCEDURE FOR MOLECULAR GEOMETRIES [J].

HEAD, JD ;

ZERNER, MC .

CHEMICAL PHYSICS LETTERS, 1985, 122 (03) :264-270

[8] SHPOLSKII EFFECT AND VIBRONIC SPECTRA OF THE PHTHALOCYANINES [J].

HUANG, TH ;

RIECKHOFF, KE ;

VOIGT, EM .

JOURNAL OF CHEMICAL PHYSICS, 1982, 77 (07) :3424-3441

[9] ENERGY TRANSFER MECHANISMS AND MOLECULAR EXCITON MODEL FOR MOLECULAR AGGREGATES [J].

KASHA, M .

RADIATION RESEARCH, 1963, 20 (01) :55-&

[10] HYPERQUENCHED GLASSY FILMS OF WATER - A STUDY BY HOLE-BURNING [J].

KIM, WH ;

REINOT, T ;

HAYES, JM ;

SMALL, GJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (19) :7300-7310