Preparation and characterization of a conjugated polymer and copper nanoparticle composite material: A chemical synthesis route

被引：15

作者：

Mallick, K

Witcomb, MJ

Scurrell, MS

机构：

[1] Univ Witwatersrand, Sch Chem, Inst Mol Sci, ZA-2050 Wits, South Africa

[2] Univ Witwatersrand, Electron Microscope Unit, ZA-2050 Wits, South Africa

来源：

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 2005年 / 123卷 / 02期

基金：

新加坡国家研究基金会;

关键词：

conjugated polymer; nanoparticles; TEM; UV-vis spectroscopy; Raman spectroscopy;

D O I：

10.1016/j.mseb.2005.07.011

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We report here on a novel in situ synthetic method for the preparation of a poly-(3,5 dimethyl aniline) and copper nanoparticle composite material. 3,5 Dimethyl aniline and copper sulfate were used as the precursors. During the reaction, 3,5 dimethyl aniline oxidizes to form poly-(3,5 dimethyl aniline), while copper sulfate is reduced and forms copper nanoparticles. The structure of the polymer was investigated using UV-vis, IR and Raman analyses. TEM and SEM studies, respectively, yielded the nanoparticle size and the morphology of the composite material. (c) 2005 Elsevier B.V. All rights reserved.

引用

收藏

页码：181 / 186

页数：6

相关论文

共 47 条

[1] PHOTOVOLTAIC AND PHOTOCONDUCTIVE PROPERTIES OF ALUMINUM POLY(P-PHENYLENE VINYLENE) INTERFACES [J].

ANTONIADIS, H ;

HSIEH, BR ;

ABKOWITZ, MA ;

JENEKHE, SA ;

STOLKA, M .

SYNTHETIC METALS, 1994, 62 (03) :265-271

[2] Self-assembly of nanoparticles into structured spherical and network aggregates [J].

Boal, AK ;

Ilhan, F ;

DeRouchey, JE ;

Thurn-Albrecht, T ;

Russell, TP ;

Rotello, VM .

NATURE, 2000, 404 (6779) :746-748

[3] Incorporation of metal nanoparticles in photopolymerized organic conducting polymers: A mechanistic insight [J].

Breimer, MA ;

Yevgeny, G ;

Sy, S ;

Sadik, OA .

NANO LETTERS, 2001, 1 (06) :305-308

[4] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].

BURROUGHES, JH ;

BRADLEY, DDC ;

BROWN, AR ;

MARKS, RN ;

MACKAY, K ;

FRIEND, RH ;

BURN, PL ;

HOLMES, AB .

NATURE, 1990, 347 (6293) :539-541

[5] COUNTERION INDUCED PROCESSIBILITY OF CONDUCTING POLYANILINE AND OF CONDUCTING POLYBLENDS OF POLYANILINE IN BULK POLYMERS [J].

CAO, Y ;

SMITH, P ;

HEEGER, AJ .

SYNTHETIC METALS, 1992, 48 (01) :91-97

[6] Copper dispersed into polyaniline films as an amperometric sensor in alkaline solutions of amino acids and polyhydric compounds [J].

Casella, IG ;

Cataldi, TRI ;

Guerrieri, A ;

Desimoni, E .

ANALYTICA CHIMICA ACTA, 1996, 335 (03) :217-225

[7] Synthesis, characterization, and optoelectronic properties of a novel polyfluorene/poly(p-phenylenevinylene) copolymer [J].

Chen, Y ;

Araki, Y ;

Doyle, J ;

Strevens, A ;

Ito, O ;

Blau, WJ .

CHEMISTRY OF MATERIALS, 2005, 17 (07) :1661-1666

[8] Synthesis and electrical properties of polymer composites with polyaniline nanoparticles [J].

Cho, MS ;

Park, SY ;

Hwang, JY ;

Choi, HJ .

MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2004, 24 (1-2) :15-18

[9] Polymer-stabilized gold nanoparticles and their incorporation into polymer matrices [J].

Corbierre, MK ;

Cameron, NS ;

Sutton, M ;

Mochrie, SGJ ;

Lurio, LB ;

Rühm, A ;

Lennox, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (42) :10411-10412

[10]

da Silva JEP, 1999, ELECTROCHIM ACTA, V44, P1887

← 1 2 3 4 5 →