Water-soluble iridium and rhodium complexes with tris(hydroxymethyl)phosphine and their catalysis in biphasic hydrogenation and hydroformylation

被引：51

作者：

Fukuoka, A

Kosugi, W

Morishita, F

Hirano, M

McCaffrey, L

Henderson, W

Komiya, S

机构：

[1] Tokyo Univ Agr & Technol, Dept Appl Chem, Koganei, Tokyo 1848588, Japan

[2] Univ Waikato, Dept Chem, Hamilton, New Zealand

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 06期

关键词：

D O I：

10.1039/a808350i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel water-soluble Ir and Rh complexes with tris(hydroxymethyl)phosphine catalyse the selective hydrogenation of the C=O bond of cinnamaldehyde and the hydroformylation of pent-1-ene both under biphasic conditions.

引用

页码：489 / 490

页数：2

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