Enzymatic synthesis and various properties of poly(catechol)

被引：79

作者：

Dubey, S ^{[1
]}

Singh, D ^{[1
]}

Misra, RA ^{[1
]}

机构：

[1] Banaras Hindu Univ, Fac Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India

来源：

ENZYME AND MICROBIAL TECHNOLOGY | 1998年 / 23卷 / 7-8期

关键词：

enzymatic polymerization; poly(catechol); peroxidase; cyclic voltammetry;

D O I：

10.1016/S0141-0229(98)00063-5

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Poly(catechol) was prepared by using peroxidase as a catalyst in two types of solvent systems: an aqueous dioxane solution and a reverse micellar solution. Peroxidases derived from two sources, horseradish (HRP) and soybean (SBP), were employed as catalyst. The structure of the prepared polymer was elucidated by infrared analysis. Enzymatically prepared film of poly(catechol) at a Pt electrode was subjected to cyclic voltammetric studies in aqueous HCl medium and phosphate buffer pH 6.5. Thermal studies of the polymer,were performed by thermogravimetric analysis. The iodine-labelled polymers showed low electrical conductivity in the range of 10(-6) to 10(-9) S cm(-1). The magnetic susceptibility and surface morphological property of the polymer were also studied. (C) 1998 Elsevier Science Inc.

引用

页码：432 / 437

页数：6

共 14 条

[1] ENZYMATIC-SYNTHESIS OF POLYANILINE FILM USING A COPPER-CONTAINING OXIDOREDUCTASE - BILIRUBIN OXIDASE [J].