Thiophene hydrodesulfurization over bimetallic and promoted nitride catalysts

被引：38

作者：

Logan, JW ^{[1
]}

Heiser, JL ^{[1
]}

McCrea, KR ^{[1
]}

Gates, BD ^{[1
]}

Bussell, ME ^{[1
]}

机构：

[1] Western Washington Univ, Dept Chem, Bellingham, WA 98225 USA

来源：

CATALYSIS LETTERS | 1998年 / 56卷 / 04期

基金：

美国国家科学基金会;

关键词：

thiophene; hydrodesulfurization; nitrides;

D O I：

10.1023/A:1019094020523

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alumina- supported bimetallic (Co3Mo3N/Al2O3) and promoted (Co-Mo2N/Al2O3) nitride catalysts have been prepared and characterized. Thiophene hydrodesulfurization (HDS) measurements show that the Co3Mo3N/Al2O3 and Co-Mo2N/Al2O3 catalysts are significantly more active than a Mo2N/Al2O3 catalyst with the same Mo loading. Furthermore, the Co-Mo2N/Al2O3 catalyst has a substantially higher HDS activity than a sulfided Co-MoO3/Al2O3 catalyst with an identical metal loading.

引用

页码：165 / 171

页数：7

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