Controlled Aqueous Atom Transfer Radical Polymerization with Electrochemical Generation of the Active Catalyst

被引：188

作者：

Bortolamei, Nicola ^{[1
]}

Isse, Abdirisak A. ^{[1
]}

Magenau, Andrew J. D. ^{[2
]}

Gennaro, Armando ^{[1
]}

Matyjaszewski, Krzysztof ^{[2
]}

机构：

[1] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy

[2] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 48期

基金：

美国安德鲁·梅隆基金会; 美国国家科学基金会;

关键词：

atom transfer radical polymerization; electrochemistry; homogeneous catalysis; polymerization; AGET ATRP; EFFICIENCY; CONSTANTS; SYSTEMS; LIGAND; MEDIA; WATER;

D O I：

10.1002/anie.201105317

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enhanced control: Electrochemically mediated atom transfer radical polymerization (ATRP) allows easy modulation of the overall rate and control of polymerization through the variation of an external applied potential, E app (see picture). This method has been successfully applied to aqueous ATRP of oligo(ethylene glycol) methyl ether methacrylate (OEOMA 475) catalyzed by Cu/tris(2-pyridylmethyl)amine. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11391 / 11394

页数：4

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