(BEDT-TTF)3Cu2(C2O4)3(CH3OH)2: an organic-inorganic hybrid antiferromagnetic semiconductor

被引：43

作者：

Zhang, Bin ^{[1
,2
]}

Zhang, Yan ^{[3
]}

Zhu, Daoben ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Organ Solid Lab, BNLMS, CMS, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China

[3] Peking Univ, Inst Condensed Matter & Mat Phys, Dept Phys, Beijing 100871, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 02期

关键词：

TO-CRYSTAL TRANSFORMATION; COMPOUND;

D O I：

10.1039/c1cc15227k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An organic-inorganic hybrid combining a semiconducting BEDT-TTF layer and a Jahn-Teller distorted oxalato-bridged honeycomb antiferromagnetic layer [Cu-2(C2O4)(3)(2-)](n) was obtained and characterized.

引用

页码：197 / 199

页数：3

共 17 条

[1]

Carlin R.L., 1977, MAGNETIC PROPERTIES

[2] Multifunctionality in hybrid magnetic materials based on bimetallic oxalate complexes [J].

Clemente-Leon, Miguel ;

Coronado, Eugenio ;

Marti-Gastaldo, Carlos ;

Romero, Francisco M. .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (02) :473-497

[3] Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound [J].

Coronado, E ;

Galán-Mascarós, JR ;

Gómez-García, CJ ;

Laukhin, V .

NATURE, 2000, 408 (6811) :447-449

[4] Two Homometallic Antiferromagnets Based on Oxalato-Bridged Honeycomb Assemblies: (A)2[MII2(C2O4)3] (A = Ammonium Salt Derived from Diethylenetriamine; MII = Fe2+, Co2+) [J].

Duan, Zhiming ;

Zhang, Yan ;

Zhang, Bin ;

Pratt, Francis L. .

INORGANIC CHEMISTRY, 2009, 48 (05) :2140-2146

[5] SYNTHESIS, ELECTRICAL-PROPERTIES, AND CRYSTAL-STRUCTURE OF THE 1ST ORGANIC METAL SOLID ELECTROLYTE HYBRID - (BEDT-TTF)3AGXI8 (X-APPROXIMATELY-6.4) [J].

GEISER, U ;

WANG, HH ;

DONEGA, KM ;

ANDERSON, BA ;

WILLIAMS, JM ;

KWAK, JF .

INORGANIC CHEMISTRY, 1986, 25 (04) :401-402

[6] BETA-(BEDT-TTF)(4)[(H2O)FE(C2O4)(3)]CENTER-DOT-PHCN - THE FIRST MOLECULAR SUPERCONDUCTOR CONTAINING PARAMAGNETIC METAL-IONS [J].

GRAHAM, AW ;

KURMOO, M ;

DAY, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (20) :2061-2062

[7] Origin of the Spin Density Wave Instability in AFe2As2 (A=Ba,Sr) as Revealed by Optical Spectroscopy [J].

Hu, W. Z. ;

Dong, J. ;

Li, G. ;

Li, Z. ;

Zheng, P. ;

Chen, G. F. ;

Luo, J. L. ;

Wang, N. L. .

PHYSICAL REVIEW LETTERS, 2008, 101 (25)

[8] Direct observation of magnetic monopole defects in an artificial spin-ice system [J].

Ladak, S. ;

Read, D. E. ;

Perkins, G. K. ;

Cohen, L. F. ;

Branford, W. R. .

NATURE PHYSICS, 2010, 6 (05) :359-363

[9] Control of Charge Transfer in a Series of Ru2II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magnetic/Conducting Materials [J].

Miyasaka, Hitoshi ;

Motokawa, Natsuko ;

Matsunaga, Satoshi ;

Yamashita, Masahiro ;

Sugimoto, Kunihisa ;

Mori, Tatsuya ;

Toyota, Naoki ;

Dunbar, Kim R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (05) :1532-1544

[10] THE INTERMOLECULAR INTERACTION OF TETRATHIAFULVALENE AND BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE IN ORGANIC METALS - CALCULATION OF ORBITAL OVERLAPS AND MODELS OF ENERGY-BAND STRUCTURES [J].

MORI, T ;

KOBAYASHI, A ;

SASAKI, Y ;

KOBAYASHI, H ;

SAITO, G ;

INOKUCHI, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (03) :627-633

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