Quantitative Study of Non-Covalent Interactions at the Electrode-Electrolyte Interface Using Cyanide-Modified Pt(111) Electrodes

被引：38

作者：

Escudero-Escribano, Maria ^{[1
]}

Zoloff Michoff, Martin E. ^{[2
]}

Leiva, Ezequiel P. M. ^{[2
]}

Markovic, Nenad M. ^{[3
]}

Gutierrez, Claudio ^{[1
]}

Cuesta, Angel ^{[1
]}

机构：

[1] CSIC, Inst Quim Fis Rocasolano, E-28006 Madrid, Spain

[2] Univ Nacl Cordoba, Fac Ciencias Quim, RA-5000 Cordoba, Argentina

[3] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA

来源：

CHEMPHYSCHEM | 2011年 / 12卷 / 12期

关键词：

density functional calculations; electrochemical double layer; non-covalent interactions; platinum; scanning probe microscopy; SCANNING-TUNNELING-MICROSCOPY; SINGLE-CRYSTAL ELECTRODES; INFRARED-SPECTROSCOPY; CARBON-MONOXIDE; METAL-CATIONS; IN-SITU; PLATINUM; SURFACE; ELECTROOXIDATION; ADSORPTION;

D O I：

10.1002/cphc.201100327

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Important interactions: Cations at the outer Helmholtz plane (OHP) can interact through non-covalent interactions with species at the inner Helmholtz plane (IHP), which are covalently bonded to the electrode surface, thereby affecting the structure and the properties of the electrochemical double layer. These non-covalent interactions can be studied quantitatively using cyanide-modified Pt(111) electrodes (see picture). © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2230 / 2234

页数：5

共 22 条

[1] Electrochemical and FTIRS characterisation of NO adlayers on cyanide-modified Pt(111) electrodes: the mechanism of nitric oxide electroreduction on Pt [J].

Cuesta, Angel ;

Escudero, Maria .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (25) :3628-3634

[2] At least three contiguous atoms are necessary for CO formation during methanol electrooxidation on platinum [J].

Cuesta, Angel .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (41) :13332-13333

[3] Cyclic Voltammetry, FTIRS, and DEMS Study of the Electrooxidation of Carbon Monoxide, Formic Acid, and Methanol on Cyanide-Modified Pt(111) Electrodes [J].

Cuesta, Angel ;

Escudero, Maria ;

Lanova, Barbora ;

Baltruschat, Helmut .

LANGMUIR, 2009, 25 (11) :6500-6507

[4] Surface Decoration at the Atomic Scale Using a Molecular Pattern: Copper Adsorption on Cyanide-Modified Pt(111) Electrodes [J].

Escudero, Maria ;

Marco, Jose F. ;

Cuesta, Angel .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (28) :12340-12344

[5] ALKALI-METAL CATIONS AND PH EFFECTS ON A SPLITTING OF THE UNUSUAL ADSORPTION STATES OF PT(111) VOLTAMMOGRAMS IN PHOSPHATE BUFFERED SOLUTIONS [J].

FELIU, JM ;

VALLS, MJ ;

ALDAZ, A ;

CLIMENT, MA ;

CLAVILIER, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 345 (1-2) :475-481

[6] Effect of pH and alkaline metal cations on the voltammetry of pt(111) single crystal electrodes in sulfuric acid solution [J].

García, N ;

Climent, V ;

Orts, JM ;

Feliu, JM ;

Aldaz, A .

CHEMPHYSCHEM, 2004, 5 (08) :1221-1227

[7] Voltammetric analysis of the co-adsorption of cyanide and carbon monoxide on a Pt(111) surface [J].

Huerta, F ;

Morallon, E ;

Vázquez, JL .

ELECTROCHEMISTRY COMMUNICATIONS, 2002, 4 (03) :251-254

[8] CYANIDE ADSORBED AS A MONOLAYER AT THE LOW-INDEX SURFACE PLANES OF PLATINUM METAL-ELECTRODES - AN IN-SITU STUDY BY INFRARED-SPECTROSCOPY [J].

KIM, CS ;

KORZENIEWSKI, C .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (38) :9784-9787

[9] Direct observation of complexation of alkali cations on cyanide-modified Pt(111) by scanning tunneling microscopy [J].

Kim, YG ;

Yau, SL ;

Itaya, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (02) :393-400

[10] [2]-CRYPTATES - STABILITY AND SELECTIVITY OF ALKALI AND ALKALINE-EARTH MACROBICYCLIC COMPLEXES [J].

LEHN, JM ;

SAUVAGE, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (23) :6700-6707

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