Bending and shaping: cubics, calamitics and columnars

被引:104
作者
Fazio, D
Mongin, C
Donnio, B
Galerne, Y
Guillon, D
Bruce, DW
机构
[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England
[2] Inst Phys & Chim Mat Strasbourg, GMO, F-67037 Strasbourg, France
关键词
D O I
10.1039/b104724h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The mesomorphism of a series of complexes of Pd( II), Pt( II) and Ag( I) is discussed and systematic structural variations are highlighted which lead to an appreciation of important factors determining the liquid-crystalline polymorphism of these complexes. Models are proposed for cubic phase formation and the occurrence of an unusual lamellar phase in-between a SmC and a columnar phase is discussed.
引用
收藏
页码:2852 / 2863
页数:12
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