trans-Dichlorobis[(R,R)-1,2-phenylenebis-(methylphenylphosphine-P)]ruthenium(II)

被引:8
作者
Hockless, DCR [1 ]
Wild, SB [1 ]
McDonagh, AM [1 ]
Whittall, IR [1 ]
Humphrey, MG [1 ]
机构
[1] AUSTRALIAN NATL UNIV,DEPT CHEM,CANBERRA,ACT 0200,AUSTRALIA
关键词
D O I
10.1107/S0108270196003009
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title complex, [RuCl2(C20H20P2)(2)], is a convenient precursor for the synthesis of interesting symmetrical or unsymmetrical optically active ruthenium sigma-acetylide complexes. The complex has trans geometry about the octahedral Ru atom, with Ru-P distances in the range 2.304 (1)-2.354 (1) Angstrom and Ru-Cl distances of 2.426 (1) and 2.432 (1) Angstrom.
引用
收藏
页码:1639 / 1641
页数:3
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