Electron interactions with c-C4F8

被引:73
作者
Christophorou, LG [1 ]
Olthoff, JK [1 ]
机构
[1] Natl Inst Stand & Technol, Elect & Elect Engn Lab, Div Elect, Gaithersburg, MD 20899 USA
关键词
attachment; c-C4F8; coefficients; cross sections; electron interactions; electron transport; ionization; perfluorocyclobutane; scattering;
D O I
10.1063/1.1372164
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The limited electron collision cross-section and transport-coefficient data for the plasma processing gas perfluorocyclobutane (C-C4F8) are synthesized, assessed, and discussed. These include cross sections for total electron scattering, differential elastic electron scattering, partial and total ionization, dissociation into neutral fragments, and electron attachment, as well as data on electron transport, ionization, and attachment coefficients. The available data on both the electron collision cross sections and the electron transport coefficients require confirmation. Also, measurements are needed of the momentum transfer and elastic integral cross sections, and of the cross sections for other. significant low-energy electron collision processes such as vibrational and electronic excitation. In addition, electron transport data over a wider range of values of the density-reduced electric field are needed. The present assessment of data on electron affinity, attachment, and scattering suggests the existence of negative ion states near - 0.6, 4.9, 6.9, 9.0, and 10.5 eV. (C) 2001 by the U.S. Secretary of Commerce on behalf of the United States. AII rights reserved.
引用
收藏
页码:449 / 473
页数:25
相关论文
共 97 条
[1]  
ALEKSEEV NV, 1972, ZH STRUKT KHIM, V15, P181
[2]  
ALEKSEEV NV, 1968, ZH STRUKT KHIM, V9, P1073
[3]   ELECTRON DISAPPEARANCE IN PULSE IRRADIATED FLUOROCARBON GASES [J].
BANSAL, KM ;
FESSENDE.RW .
JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (04) :1760-1768
[4]   MOLECULAR STRUCTURES OF DODECAFLUORO-CYCLOHEXANE AND DECAFLUORO-CYCLOPENTANE [J].
BASTIANSEN, O ;
HASSEL, O ;
LUND, LK .
ACTA CHEMICA SCANDINAVICA, 1949, 3 (03) :297-298
[5]   SPECTRA AND STRUCTURE OF PERFLUOROCYCLOBUTANE [J].
BAUMAN, RP ;
BULKIN, BJ .
JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (02) :496-&
[6]   THE MOLECULAR-STRUCTURE OF PERFLUORO-THIIRANE IN THE PRESENCE OF PERFLUORO-CYCLOBUTANE - A GAS-PHASE ELECTRON-DIFFRACTION STUDY [J].
BEAGLEY, B ;
CALLADINE, R ;
PRITCHARD, RG ;
TAYLOR, SF .
JOURNAL OF MOLECULAR STRUCTURE, 1987, 158 :309-314
[7]   MOLECULAR ELECTRON IONIZATION CROSS SECTIONS AT 70-EV [J].
BERAN, JA ;
KEVAN, L .
JOURNAL OF PHYSICAL CHEMISTRY, 1969, 73 (11) :3866-&
[8]  
Berril J, 1987, GASEOUS DIELECTRICS, P304
[9]   IONIZATION AND DISSOCIATION IN SOME FLUOROCARBON GASES [J].
BIBBY, MM ;
CARTER, G .
TRANSACTIONS OF THE FARADAY SOCIETY, 1963, 59 (491) :2455-&
[10]  
BRUBAKER S, 1974, ARCH OPHTHALMOL-CHIC, V92, P324