Dehydration of hydroxenin monoacetate in the presence of ultrasound

被引:5
作者
Aquino, F [1 ]
Bonrath, W [1 ]
机构
[1] F Hoffmann La Roche & Co Ltd, Vitamins & Fine Chem Div, CH-4070 Basel, Switzerland
关键词
hydroxenin monoacetate; vitamin A; polyenes; dehydration; isomerisation; ultrasound;
D O I
10.1016/S1350-4177(00)00076-6
中图分类号
O42 [声学];
学科分类号
070206 ; 082403 ;
摘要
Starting from hydroxenin monoacetate, vitamin A acetate is obtained in a E/Z mixture by dehydration. This result could be explained by the formation of a small amount of hydrochloric acid from trichloromethane under ultrasound irradiation and based on further experiments. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:217 / 220
页数:4
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