Calix[4]arene derivatives as stationary phases for capillary gas chromatography

被引：33

作者：

Lin, L ^{[1
]}

Wu, CY ^{[1
]}

Yan, ZQ ^{[1
]}

Yan, XQ ^{[1
]}

Su, XL ^{[1
]}

Han, HM ^{[1
]}

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Hubei Province, Peoples R China

来源：

CHROMATOGRAPHIA | 1998年 / 47卷 / 11-12期

关键词：

gas chromatography; stationary phases; calix[4]arene derivatives;

D O I：

10.1007/BF02467455

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Two new kinds of calix[4]arene derivatives, 5,11,17,23-tetra-tert-butyl-25,27-bis(isopropylcarbamoyl-methoxy)-26,28-diundecenyloxy calix[4]arene (C[4]A) and 25,27-dibutoxy-5,11,17,23-tetra-tert-butyl-26,28-di-undecenyloxy calix[4]arene (C[4]B), have been synthesized for use as stationary phases in capillary gas chromatography with OV1701. These stationary phases demonstrate high column efficiencies, wide operating temperature ranges, good thermal stability and excellent selectivity for aromatic isomers, especially phenol compounds Their inclusion properties are also discussed.

引用

页码：689 / 694

页数：6

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