Incorporation of imidazole within the metal-organic framework UiO-67 for enhanced anhydrous proton conductivity

被引：104

作者：

Liu, Shucheng ^{[1
]}

Yue, Zifeng ^{[1
]}

Liu, Yi ^{[1
]}

机构：

[1] Guizhou Univ, Coll Sci, Guiyang 550025, Peoples R China

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 29期

基金：

中国国家自然科学基金;

关键词：

POLYMER;

D O I：

10.1039/c5dt01667c

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

Imidazole was introduced into the channels of the metal-organic framework UiO-67 using an evaporation method. The imidazole@UiO-67 composite presents a high proton conductivity of 1.44 x 10(-3) S cm(-1) at 120 degrees C under anhydrous conditions. With a low activation energy at high temperatures (0.36 eV), the hybrid material can be regarded as a superionic conductor.

引用

页码：12976 / 12980

页数：5

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