Synthesis and characterization of conducting polyaniline-coated cadmium sulphide nanocomposites in reverse microemulsion

被引：125

作者：

Khiew, PS ^{[1
]}

Huang, NM ^{[1
]}

Radiman, S ^{[1
]}

Ahmad, MS ^{[1
]}

机构：

[1] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Appl Phys, Nucl Sci Program, Bangi 43600, Selangor, Malaysia

来源：

MATERIALS LETTERS | 2004年 / 58卷 / 3-4期

关键词：

nanocomposites; polymers; semiconductor; microemulsion; electron microscopy; infrared spectroscopy;

D O I：

10.1016/S0167-577X(03)00537-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

II-VI group of semiconductor cadmium sulphide (CdS) nanocrystalline, Which Were coated with conducting polyaniline (PANI), have been prepared by microemulsion processing technique. The synthesized polyaniline-coated CdS nanocomposites were characterized by UV-Vis absorption spectroscopy, energy filter transmission electron microscopy (EFTEM), FTIR spectroscopy and TGA analysis. The UV-Vis spectrums revealed the enhancement of doping level for the nanocomposites, which is assigned to the existence of greater number of charges on the polymer backbone. The FTIR spectra indicated that the polymers were highly doped and existed in conducting emeraldine salt form. The as-prepared PANI/CdS nanocomposites were polydispersed and have an average size of ca. 17.8 nm. The obtained CdS/PANI nanocomposites showed significant improvement in the thermal behavior as indicated in the TGA thermograph. (C) 2003 Elsevier B.V. All. rights reserved.

引用

页码：516 / 521

页数：6

共 28 条

[1] Synthesis and structural characterisation of CdS nanoparticles prepared in a four-components "water-in-oil" microemulsion [J].