Microwave activation of electrochemical processes at microelectrodes

被引：75

作者：

Compton, RG ^{[1
]}

Coles, BA ^{[1
]}

Marken, F ^{[1
]}

机构：

[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 23期

关键词：

D O I：

10.1039/a806511j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical experiments at platinum microdisc electrodes are shown to be possible in an environment of intense microwave radiation and a considerable current enhancement observed for the ferrocyanide/ferricyanide redox couple in aqueous 1 M KCI is shown to be Faradaic in nature consistent with a rapid heating effect causing the temperature in the liquid phase at the electrode/solution interface to locally superheat.

引用

页码：2595 / 2596

页数：2

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