Speed of sound of n-hexane and n-hexadecane at temperatures between 298 and 373 K and pressures up to 100 MPa

被引:86
作者
Ball, SJ [1 ]
Trusler, JPM [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn & Chem Technol, London SW7 2BY, England
基金
英国工程与自然科学研究理事会;
关键词
acoustic; hexadecane; hexane; pulse-echo method; speed of sound;
D O I
10.1023/A:1010770730612
中图分类号
O414.1 [热力学];
学科分类号
摘要
Measurements of the speed of Sound It for n-hexane and rr-hexadecane Lit temperatures of 298.3, 323.15, 348.15, and 373.15 K and at pressures up to 100 MPa are reported. The speeds of sound, the temperatures, and the pressures are subject to an uncertainty of +/-0.1%, +/-0.01 K, and +/-0.2 MPa, respectively. These measurements were undertaken using a nea apparatus which has been constructed for measurement of the speed of sound in liquids and supercritical fluids at pressures up to 200 MPa and at temperatures between 248 and 473 K. The technique is bused on a pulse-echo method with a single transducer placed between two plane parallel reflectors. The speed of sound is obtained fi om the difference between the round-trip transit times in the two paths. It is expected that both the precision and the accuracy of the method can be further improved.
引用
收藏
页码:427 / 443
页数:17
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