Solvent free permanganate oxidations

被引：149

作者：

Shaabani, A

Lee, DG ^{[1
]}

机构：

[1] Univ Regina, Dept Chem & Biochem, Regina, SK S4S 0A2, Canada

[2] Shahid Beheshti Univ, Tehran, Iran

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 34期

基金：

加拿大自然科学与工程研究理事会;

关键词：

oxidation; permanganate; solvent free; thiols; sulfides; alcohols; diols; ethers; arenes;

D O I：

10.1016/S0040-4039(01)01129-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidations of organic compounds by permanganate under solvent free conditions have been studied. Thiols and primary aromatic amines undergo oxidative coupling reactions to give disulfides and diazenes, respectively, sulfides are oxidized to sulfones, primary and secondary alcohols are converted to aldehydes and ketones, 1,4-diols and cyclic ethers give lactones and arenes are oxidized to the corresponding a-ketones. The experimental procedure is simple and the products are easily isolated in good yields. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：5833 / 5836

页数：4

共 20 条

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