Plasma electrolytic oxidation and corrosion protection of Zircaloy-4

被引:90
作者
Cheng, Y. [2 ]
Matykina, E. [3 ]
Arrabal, R. [3 ]
Skeldon, P. [1 ]
Thompson, G. E. [1 ]
机构
[1] Univ Manchester, Sch Mat, Ctr Corros & Protect, Manchester M13 9PL, Lancs, England
[2] Hunan Univ, Coll Mat Sci & Engn, Changsha 410082, Hunan, Peoples R China
[3] Univ Complutense Madrid, Fac Ciencias Quim, Dpt Ciencia Mat & Ingn Metalurg, E-28040 Madrid, Spain
基金
英国工程与自然科学研究理事会; 美国国家科学基金会;
关键词
Plasma electrolytic oxidation; Zircaloy-4; Nitric acid; Potentiodynamic polarization; ZIRCONIUM ALLOY; CERAMIC COATINGS; TERNARY-SYSTEM; OXIDE-FILMS; MICROSCOPY;
D O I
10.1016/j.surfcoat.2012.01.011
中图分类号
TB3 [工程材料学];
学科分类号
082905 [生物质能源与材料];
摘要
The compositions and morphologies of coatings formed by plasma electrolytic oxidation (PEO) on Zircaloy-4 in silicate electrolyte, using an AC current regime, have been determined for a range of formation times. The coatings consist of zirconia with incorporated silicon species, with the distributions of coating species related to the types of discharges. Potentiodynamic polarization in 6 M nitric acid at 100 degrees C indicated that the corrosion resistance is mainly provided by the thin barrier layer next to the substrate. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:3230 / 3239
页数:10
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