Photocatalytic hydrogen generation and decomposition of oxalic acid over platinized TiO2

被引:244
作者
Li, YX [1 ]
Lu, GX [1 ]
Li, SB [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
关键词
photocatalysis; hydrogen generation; oxalic acid; Pt-TiO2;
D O I
10.1016/S0926-860X(01)00491-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photocatalytic hydrogen evolution using oxalic acid as electron donor has been investigated over Pt-TiO2 prepared by photodeposition. The reaction kinetics is consistent with the Langmuir model. The effects of pH. amount of deposited Pt and additives of inorganic anions on the rate of the reaction were also studied. A possible reaction mechanism was discussed. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:179 / 185
页数:7
相关论文
共 31 条
[1]   EFFECTS OF COMMON INORGANIC ANIONS ON RATES OF PHOTOCATALYTIC OXIDATION OF ORGANIC-CARBON OVER ILLUMINATED TITANIUM-DIOXIDE [J].
ABDULLAH, M ;
LOW, GKC ;
MATTHEWS, RW .
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (17) :6820-6825
[2]   Electron source in photoinduced hydrogen production on Pt-supported TiO2 particles [J].
Abe, T ;
Suzuki, E ;
Nagoshi, K ;
Miyashita, K ;
Kaneko, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (07) :1119-1123
[3]  
BILLING R, 1990, TOP CURR CHEM, V158, P151
[4]   EFFECT OF PLATINUM DEPOSITS ON OXYGEN-ADSORPTION AND OXYGEN ISOTOPE EXCHANGE OVER VARIOUSLY PRETREATED, ULTRAVIOLET-ILLUMINATED POWDER TIO2 [J].
COURBON, H ;
HERRMANN, JM ;
PICHAT, P .
JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (22) :5210-5214
[5]  
DIMETRIJEVIC NM, 1984, J AM CHEM SOC, V106, P6565
[6]   PLATINUM TITANIUM-DIOXIDE CATALYSTS - A PHOTOCONDUCTIVITY STUDY OF ELECTRON-TRANSFER FROM THE ULTRAVIOLET-ILLUMINATED SUPPORT TO THE METAL AND OF THE INFLUENCE OF HYDROGEN [J].
DISDIER, J ;
HERRMANN, JM ;
PICHAT, P .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1983, 79 :651-660
[7]  
DOMENECH J, 1987, J CHEM RES-S, P360
[8]   COMPETITION STUDIES OF HYDROXYL RADICAL REACTIONS IN SOME GAMMA-RAY IRRADIATED AQUEOUS SOLUTIONS AT DIFFERENT PH VALUES [J].
DRAGANIC, ZD ;
KOSANIC, MM ;
NENADOVICA, MT .
JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (08) :2390-+
[9]   CHEMISTRY OF TITANIUM DIOXIDE SURFACE .3. REACTIONS OF BASIC HYDROXYL ON SURFACE [J].
FLAIGBAUMANN, R ;
HERRMANN, M ;
BOEHM, HP .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1970, 372 (03) :296-+
[10]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+