Thermal properties of mixed alkali bis(trifluoromethylsulfonyl)amides

被引:107
作者
Hagiwara, Rika [1 ]
Tamaki, Kenichiro [1 ]
Kubota, Keigo [1 ]
Goto, Takuya [1 ]
Nohira, Toshiyuki [1 ]
机构
[1] Kyoto Univ, Grad Sch Energy Sci, Sakyo Ku, Kyoto 6068501, Japan
关键词
D O I
10.1021/je700368r
中图分类号
O414.1 [热力学];
学科分类号
摘要
Phase diagrams of binary mixtures of alkali bis(trifluoromethylsulfonyl)amides have been constructed, and their eutectic compositions and temperatures have been determined. It has been revealed that the molten salt electrolytes having the melting points in the intermediate temperature range (373 to 473) K are easily formed by simple mixing of two kinds of single alkali bis(trifluoromethylsulfonyl)amide salts. The 1:1 or 3:1 double salt is occasionally formed for some binary systems.
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页码:355 / 358
页数:4
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